Gear Fourth is a technique first seen in Luffy's battle against Donquixote Doflamingo. It was developed by Luffy during his training on Rusukaina. Luffy coats his arm in Busoshoku Haki before biting into his forearm. Similar to how he activates Gear Third, he blows an incredible amount of air into his body, but this time he inflates his muscular structure before distributing the air throughout his body, with emphasis on his upper half. Unlike other gears, Gear 4th has few forms, in which Luffy can transform into. So today, lets count all the forms of Gear 4th.
1. Bounceman
Luffy's first Gear Fourth form is called Boundman or Bounceman. Luffy's proportions become warped and his body becomes much larger in size, with his arms, upper torso, and legs coated in Busoshoku Haki. As a side-effect, he is incapable of standing still on the ground, and instead constantly bounces on the spot. This form was created in order to combat the many powerful and large animals on Rusukaina.
This form, much like Gear Second, seems to utilize the principles of Rokushiki. It possesses both high speed movement reminiscent of Soru and the ability to kick off the air, similar to Geppo, cleverly adapted to work even better with his body's elasticity: Luffy not only bounces off the air, but allows attacks to bounce off his own body. His body is also now strong enough to defend against cutting attacks head-on.
This form, much like Gear Second, seems to utilize the principles of Rokushiki. It possesses both high speed movement reminiscent of Soru and the ability to kick off the air, similar to Geppo, cleverly adapted to work even better with his body's elasticity: Luffy not only bounces off the air, but allows attacks to bounce off his own body. His body is also now strong enough to defend against cutting attacks head-on.
2. Tankman
Due to the increase in Luffy's metabolism Gear Fourth causes, he is able to leave his Tankman form in a short time after using it. This is the case when Luffy was able to burn off the massive amount of biscuits he had eaten in his fight with Cracker shortly after he defeated the Sweet Commander.
Currently, the base form of "Tankman" is unknown, since the only time it has been used was after Luffy ate Cracker's Biscuits to the point where he was completely full and used his "Manpuku Version" form.
3. Snakeman
In this form, Luffy gains a significant increase in speed and ability to use "Python" to change the direction of his attacks, the latter of which he also possesses in his Boundman form. However, Snakeman allows his attacks to continuously accelerate the longer they last, allowing Luffy not only to press an attack more fiercely on an opponent capable of dodging but also to increase the attack's speed and power until he finally lands the hit. It also gives him the opportunity to attack any area of an opponent with ease. This form focuses on dealing with agile opponents who specialize in dodging and requires Luffy's recently heightened proficiency in Kenbunshoku Haki in order to make his punches into semi-homing attacks.
This is it, I hope you enjoyed!